X-Ray crystal structure of [(?-H)Os2 (CO)4 (SnPh3)2 (?-HSnPh2) (?-dppf)] (dppf = 1,1´-bis (Diphenylphosphino) ferrocene

Authors

  • Jagodish C Sarker Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342
  • Md Saifur Rahman Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342
  • Shariff E Kabir Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342
  • Tasneem A Siddiquee Department of Chemistry, Tennessee State University, 3500 John A. Merritt Blvd. Nashville TN 37209

DOI:

https://doi.org/10.3329/jbas.v38i1.20218

Keywords:

Bimetallic, Osmium-tin cluster, Diphosphine, Crystal structure

Abstract

The solid-state molecular structure determination of the bimetallic osmium-tin compound [(?-H)Os2(CO)4(SnPh3)2(?-HSnPh2)(?-dppf)] (1) was carried out to determine the relative orientationof the coordinated ligands. Compound 1 crystallizes in the monoclinic space group P 21/c with a =22.366(7), b = 14.217(4), c = 25.213(8) Å, ? = 98.865(7)°, Z = 8 and V = 7921(4) Å3. It is a 34-electron bimetallic cluster with the Os-Os edge concomitantly bridged by a dppf and two HSnPh2 ligands

DOI: http://dx.doi.org/10.3329/jbas.v38i1.20218

Journal of Bangladesh Academy of Sciences, Vol. 38, No. 1, 97-101, 2014

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Published

2014-08-27

How to Cite

Sarker, J. C., Rahman, M. S., Kabir, S. E., & Siddiquee, T. A. (2014). X-Ray crystal structure of [(?-H)Os2 (CO)4 (SnPh3)2 (?-HSnPh2) (?-dppf)] (dppf = 1,1´-bis (Diphenylphosphino) ferrocene. Journal of Bangladesh Academy of Sciences, 38(1), 97–101. https://doi.org/10.3329/jbas.v38i1.20218

Issue

Vol. 38 No. 1 (2014)

Section

Short Communication