Microwave assisted co-operative dynamics and structural variations in chlorobenzene-acetonitrile solutions

Authors

  • SS Birajdar Department of Physics and Electronics, Maharashtra Udayagiri Mahavidyalaya, Udgir, Maharashtra, India-413517
  • JW Gaikwad Rajaram Shinde Institute of Engineering and Technology, Pedhambe, Maharashtra, India-415603
  • DB Suryawanshi Department of Physics and Electronics, Shri Havagiswami Mahavidyalaya, Udgir, Maharashtra, India-413517

DOI:

https://doi.org/10.3329/bjsir.v57i2.60404

Keywords:

Static dielectric permittivity; Excess permittivity; Kirkwood correlation factor; Luzar model; Bruggeman factor; X-band technique

Abstract

Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitrile) molecule and Cl (chlorine) molecule of CBZ and ACN binary solutions has been studied using X-band microwave technique at 301ºK. Co-operative dynamics and hydrogen bonding between nitrile and chlorine group molecules has been thoroughly explicated thereby obtaining static dielectric constant, excess permittivity, Kirkwood correlation factor using Luzar model and Bruggeman factor.

Bangladesh J. Sci. Ind. Res. 57(2), 85-90, 2022

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Published

2022-06-26

How to Cite

Birajdar, S., Gaikwad, J., & Suryawanshi, D. (2022). Microwave assisted co-operative dynamics and structural variations in chlorobenzene-acetonitrile solutions. Bangladesh Journal of Scientific and Industrial Research, 57(2), 85–90. https://doi.org/10.3329/bjsir.v57i2.60404

Issue

Vol. 57 No. 2 (2022)

Section

Articles

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