Comparative Study of Molecular Interaction in Ternary Liquid Mixtures of Polar and Non-Polar Solvents

Authors

  • B. Samantaray Department of Chemistry, Ravenshaw University, Cuttack, Odisha, India; Department of Chemistry, Odisha University of Technology and Research, Odisha, India
  • M. K. Praharaj Deaprtment of Physics, Ajay Binay Institute of Technology, Cuttack, Odisha, India https://orcid.org/0000-0002-9628-8605
  • B. R. Das Department of Chemistry, Odisha University of Technology and Research, Odisha, India
  • S. P. Das Department of Chemistry, Ravenshaw University, Cuttack, Odisha, India

DOI:

https://doi.org/10.3329/jsr.v14i3.57587

Abstract

Ultrasonic velocity measurements, density measurements, and viscometric studies were conducted for the ternary mixture of pyridine and toluene separately with N, N-dimethylformamide (DMF) in butanol, at different temperatures and for different concentrations of component liquids. Using these basic experimental data, various acoustic and thermodynamic parameters, such as adiabatic compressibility (β), free length (Lf,), free volume (Vf), etc. were calculated. Also, Excess thermo-acoustical parameters were calculated from the experimentally measured data. The outcomes were expressed in terms of the molecular interactions and the variations in parameters under varying solute concentrations. A comparative study is discussed. Variation in the above parameters for the different mixtures is indicative of the nature of the interactions between the components in the liquid mixture. Concluding remarks regarding intermolecular interactions are provided.

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Published

2022-09-01

How to Cite

Samantaray, B., Praharaj, M. K., Das, B. R., & Das, S. P. (2022). Comparative Study of Molecular Interaction in Ternary Liquid Mixtures of Polar and Non-Polar Solvents. Journal of Scientific Research, 14(3), 917–929. https://doi.org/10.3329/jsr.v14i3.57587

Issue

Section

Section B: Chemical and Biological Sciences